et al. As with all safety regulations, the safe work exposure limits for ammonia vary from region to region. C = Ceiling limit. Asthmatics or individuals with other breathing problems may be more sensitive to the effects of ammonia. Ammonia has a strong smell, similar to urine, which can be detected by most people even in small amounts. Exposure to a substance is uptake into the body. NH3 has an odor threshold of 5-50 ppm and can cause eye irritation at 20 ppm, therefore its presence may be sensed in concentrations below the exposure limits. A WES for a particular chemical sets out the legal concentration limit of that chemical that must not be exceeded. Irritation to eyes, nose and throat after 2 hours exposure . This reaction is known as the Haber-Bosch process. WorkSafeBC maintains the Table of Exposure Limits for Chemical and Biological Substances, which lists all substances with a B.C. The concentration These documents provide information on the health effects of exposure, the chemical’s toxicity and material for responding to a chemical incident. ], inhalation, ingestion (solution), skin and/or eye contact (solution/liquid), irritation eyes, nose, throat; dyspnea (breathing difficulty), wheezing, chest pain; pulmonary edema; pink frothy sputum; skin burns, vesiculation; liquid: frostbite, Centers for Disease Control and Prevention. This is based on a full shift, 8-hour time weighted average (TWA) exposure. Traditionally, the concentration at which individuals start to perceive an odor has been determined using threshold detection procedures that involve a forced-choice between blanks and odorant stimuli at varyi… In the home, ammonia is used in certain cleaning products and garden fertilisers. [Note: Shipped as a liquefied compressed gas. 35 ppm ; Maximum allowable short-term (15 minutes) exposure limit . Up to 250 ppm: (APF = 10) Any chemical cartridge respirator with cartridge(s) providing protection against the compound of concern*(APF = 10) Any supplied-air respirator*, Up to 300 ppm: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode*(APF = 25) Any powered, air-purifying respirator with cartridge(s) providing protection against the compound of concern*(APF = 50) Any chemical cartridge respirator with a full facepiece and cartridge(s) providing protection against the compound of concern(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern(APF = 50) Any self-contained breathing apparatus with a full facepiece(APF = 50) Any supplied-air respirator with a full facepiece, Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus, Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concernAny appropriate escape-type, self-contained breathing apparatus, Important additional information about respirator selection, Anhydrous ammonia, Aqua ammonia, Aqueous ammonia
Ammonia is a colourless, reactive gas that is lighter than air (approximately half as heavy) which dissolves readily in water. Refer to 29 CFR 1910.134 and ANSI: Z9.2 for requirements and selection. RESPIRATORY PROTECTION: Respiratory protection approved by NIOSH for ammonia must be used when applicable safety and health exposure limits are exceeded. If you have got ammonia on your skin, remove soiled clothing (not over the head), wash the affected area with lukewarm water and soap for at least 10 to 15 minutes and seek medical advice. Ammonia Exposure Limits. Splashes in the eye may cause damage which may be irreversible in some cases and can Workplace Exposure Limits OSHA: The legal airborne permissible exposure limit (PEL) is 50 ppm averaged over an 8-hour workshift. The concentration was quite high at the time of the incident. 300 ppm or more ; Immediately dangerous to life and health (IDLH) concentration. 5–10 Irritant b . STEL = Short-term Exposure Limit. For escape in emergencies, NIOSH approved respiratory protection should be used, such as a full-face gas mask and canisters/cartridges approved for ammonia or SCBA. OSHA recognizes that many of its permissible exposure limits (PELs) are outdated and inadequate for ensuring protection of worker health. The risk of harmful ammonia exposure to humans can occur during professional or personal use. Workplace exposure standards (WES) in Australia cover approximately 700 chemicals. OSHA’s former exposure limit for ammonia was 50 ppm as an 8-hour TWA. Asthmatics or individuals with other breathing problems may be more sensitive to the effects of ammonia. In the home, exposure may occur from certain cleaning agents and dyes; however exposure is likely to be minimal if the products are used appropriately. Acute exposure guideline levels (AEGLs) describe the human health effects from once-in-a-lifetime, or rare, exposure to airborne chemicals. [Note: Corrosive to copper & galvanized surfaces. 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